Memory

With the miniaturization and high integration of semiconductor devices,
it is becoming more and more important to evaluate with high spatial resolution and sensitivity.
Among them, there are challenges in forming uniformly shaped holes, controlling film thickness/coatability, and reducing contamination. In order to address these issues,
it is possible to obtain more effective data by performing a combined analysis that combines various analytical methods and simulations, rather than evaluating a single method.
Examples of memory material evaluations are shown below.

メモリ

Reverse engineering of DRAM in a product

The analysis of DRAM, a typical memory, is consistent from the product level to the analysis of microstructure by TEM observation.
From the appearance observation, layer analysis, and slice & view, the overall structure was grasped,
and the microstructure of the memory part was observed on TEM images.

製品内のDRAMのリバースエンジニアリング

Evaluation of contamination of electronic components by adhesive sheets

In the manufacturing process of semiconductor devices, various adhesive sheets such as dicing tapes are used.
The adhesive sheet may cause foreign matter or contamination.
In this case study, we introduce the results of a combined evaluation using TOF-SIMS and SWA-GC/MS, where it is possible to identify which adhesive sheet and which layer of the adhesive sheet is responsible for the foreign matter/contamination by performing qualitative analysis of each adhesive sheet material.
In addition,SWA-GC/MS can quantitatively confirm which adhesive sheet is the least contaminated.

粘着シートによる電子部品の汚染評価

Evaluation of compositional distribution of ultra-thin films by Angle-Resolved XPS (ARXPS)

Angle-Resolved XPS (ARXPS) is a method to detect photoelectrons emitted by X-ray irradiation at each extraction angle and to evaluate the depth profile near the sample surface using spectra with different detection depths.
Compared to the conventional Ar ion sputtering method, this method has the advantage of improved depth resolution and no compositional changes due to selective sputtering or mixing, and is effective for evaluating the depth profile of ultra-thin films (several nm) on substrates.

角度分解XPS(ARXPS)による極薄膜の組成分布評価

Structural analysis of amorphous SiNx films using molecular dynamics simulations

Amorphous SiNx (a-SiNx) films are used in a wide range of applications, such as gate insulators for transistors,
because the physical properties of amorphous SiNx (a-SiNx) films vary greatly from semiconductors to insulators depending on the compositional changes in the N/Si ratio and other factors. On the other hand, there are only a few experimental methods to analyze the microscopic structure of amorphous materials at the atomic level,
so it is an effective tool to create and analyze amorphous structures with various compositions and densities by simulation.

分子動力学計算を用いたアモルファスSiNx膜の構造解析

Click here to see the power device analysis case study.

評価対象 評価項目 部位 Analysis Method
表面保護膜 膜厚・形状 実製品 SEMTEM
膜質(水素濃度・組成) 実製品 SIMS
バルク・薄膜 SIMSFT‐IR
配線・層間絶縁膜 配線・層間絶縁膜の組成 実製品 AESTEM‐EDXEELS
バルク・薄膜 XPSRBS
配線・層間絶縁膜の寸法 実製品 SEMTEM
配線内の結晶粒 実製品 EBSDTEMED
異物 実製品 AESTEM‐EDXSlice&View
配線金属成分の拡散 バルク・薄膜 SIMS
断線・短絡箇所特定 実製品 EMSOBIRCHロックイン発熱
配線金属の化学結合状態評価 バルク・薄膜 XPS
ゲート電極 ゲート電極の寸法 実製品 TEM
ゲート電極の組成 実製品 TEM‐EDXEELS
ゲート電極成分の拡散 バルク・薄膜 SIMS
ゲート絶縁膜 絶縁膜の寸法 実製品 TEM
絶縁膜の組成 実製品 TEM‐EDXEELS
絶縁膜の不純物濃度分布 バルク・薄膜 SIMS
絶縁膜の化学結合状態評価 バルク・薄膜 XPS
絶縁膜の密度評価 バルク・薄膜 XRR
拡散層 ドーパント分布評価 バルク・薄膜 SIMS
キャリア分布評価 バルク・薄膜 SRA
拡散層形状評価 実製品 SCMSMMSSRM
結晶欠陥評価 実製品 TEM
基板 ウエハ表面汚染評価 バルク・薄膜 XPSTOF‐SIMSICP‐MS
結晶性評価 バルク・薄膜 XRD
結晶欠陥評価 バルク・薄膜 PLTEM
応力評価 バルク・薄膜 RamanXRD
実製品 TEMED
不純物分布評価 バルク・薄膜 SIMS

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Temuzo&Masumin